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Zeroth law of thermodynamics

The zeroth law of thermodynamics states that if two thermodynamic systems are each in thermal equilibrium with a third system, then they are in thermal equilibrium with each other. Accordingly, thermal equilibrium between systems is a transitive relation.

Two systems are said to be in thermal equilibrium with respect to each other if they are linked by a wall permeable only to heat and they do not change over time. As a convenience of language, the same is also sometimes said of unlinked systems that would not change if they did have such a wall.

Another formulation by Maxwell is "All heat is of the same kind". Another statement of the law is "All diathermal walls are equivalent".: 24, 144

The law is important for the mathematical formulation of thermodynamics. Mathematically, the zeroth law makes the relation of thermal equilibrium between systems an equivalence relation, which is precisely the type of relation that can represent equality of some quantity associated to each system. A quantity that is the same for two systems if and only if they can be placed in thermal equilibrium with each other is a scale of temperature; the zeroth law is needed in order for there to exist any (and therefore many) such scales. The condition justifies the use of practical thermometers.: 56

Contents

A thermodynamic system is by definition in its own state of internal thermodynamic equilibrium, that is to say, there is no change in its observable state (i.e. macrostate) over time and no flows occur in it. One precise statement of the zeroth law is that the relation of thermal equilibrium is an equivalence relation on pairs of thermodynamic systems.: 52 In other words, the set of all systems each in its own state of internal thermodynamic equilibrium may be divided into subsets in which every system belongs to one and only one subset, and is in thermal equilibrium with every other member of that subset, and is not in thermal equilibrium with a member of any other subset. This means that a unique "tag" can be assigned to every system, and if the "tags" of two systems are the same, they are in thermal equilibrium with each other, and if different, they are not. This property is used to justify the use of empirical temperature as a tagging system. Empirical temperature provides further relations of thermally equilibrated systems, such as order and continuity with regard to "hotness" or "coldness", but these are not implied by the standard statement of the zeroth law.

If it is defined that a thermodynamic system is in thermal equilibrium with itself (i.e., thermal equilibrium is reflexive), then the zeroth law may be stated as follows:

If a body C, be in thermal equilibrium with two other bodies, A and B, then A and B are in thermal equilibrium with one another.

This statement asserts that thermal equilibrium is a left-Euclidean relation between thermodynamic systems. If we also define that every thermodynamic system is in thermal equilibrium with itself, then thermal equilibrium is also a reflexive relation. Binary relations that are both reflexive and Euclidean are equivalence relations. Thus, again implicitly assuming reflexivity, the zeroth law is therefore often expressed as a right-Euclidean statement:

If two systems are in thermal equilibrium with a third system, then they are in thermal equilibrium with each other.

One consequence of an equivalence relationship is that the equilibrium relationship is symmetric: If A is in thermal equilibrium with B, then B is in thermal equilibrium with A. Thus we may say that two systems are in thermal equilibrium with each other, or that they are in mutual equilibrium. Another consequence of equivalence is that thermal equilibrium is a transitive relationship and is occasionally expressed as such:: 56

If A is in thermal equilibrium with B and if B is in thermal equilibrium with C, then A is in thermal equilibrium with C .

A reflexive, transitive relationship does not guarantee an equivalence relationship. In order for the above statement to be true, both reflexivity and symmetry must be implicitly assumed.

It is the Euclidean relationships which apply directly to thermometry. An ideal thermometer is a thermometer which does not measurably change the state of the system it is measuring. Assuming that the unchanging reading of an ideal thermometer is a valid tagging system for the equivalence classes of a set of equilibrated thermodynamic systems, then the systems are in thermal equilibrium, if a thermometer gives the same reading for each system. If the system are thermally connected, no subsequent change in the state of either one can occur. If the readings are different, then thermally connecting the two systems causes a change in the states of both systems. The zeroth law provides no information regarding this final reading.

Nowadays, there are two nearly separate concepts of temperature, the thermodynamic concept, and that of the kinetic theory of gases and other materials.

The zeroth law belongs to the thermodynamic concept, but this is no longer the primary international definition of temperature. The current primary international definition of temperature is in terms of the kinetic energy of freely moving microscopic particles such as molecules, related to temperature through Boltzmann's constant k B {\displaystyle k_{\mathrm {B} }} . The present article is about the thermodynamic concept, not about the kinetic theory concept.

The zeroth law establishes thermal equilibrium as an equivalence relationship. An equivalence relationship on a set (such as the set of all systems each in its own state of internal thermodynamic equilibrium) divides that set into a collection of distinct subsets ("disjoint subsets") where any member of the set is a member of one and only one such subset. In the case of the zeroth law, these subsets consist of systems which are in mutual equilibrium. This partitioning allows any member of the subset to be uniquely "tagged" with a label identifying the subset to which it belongs. Although the labeling may be quite arbitrary, temperature is just such a labeling process which uses the real number system for tagging. The zeroth law justifies the use of suitable thermodynamic systems as thermometers to provide such a labeling, which yield any number of possible empirical temperature scales, and justifies the use of the second law of thermodynamics to provide an absolute, or thermodynamic temperature scale. Such temperature scales bring additional continuity and ordering (i.e., "hot" and "cold") properties to the concept of temperature.

In the space of thermodynamic parameters, zones of constant temperature form a surface, that provides a natural order of nearby surfaces. One may therefore construct a global temperature function that provides a continuous ordering of states. The dimensionality of a surface of constant temperature is one less than the number of thermodynamic parameters, thus, for an ideal gas described with three thermodynamic parameters P, V and N, it is a two-dimensional surface.

For example, if two systems of ideal gases are in joint thermodynamic equilibrium across an immovable diathermal wall, thenP1V1/N1 = P2V2/N2 where Pi is the pressure in the ith system, Vi is the volume, and Ni is the amount (in moles, or simply the number of atoms) of gas.

The surface PV/N = constant defines surfaces of equal thermodynamic temperature, and one may label defining T so that PV/N = RT, where R is some constant. These systems can now be used as a thermometer to calibrate other systems. Such systems are known as "ideal gas thermometers".

In a sense, focused on in the zeroth law, there is only one kind of diathermal wall or one kind of heat, as expressed by Maxwell's dictum that "All heat is of the same kind". But in another sense, heat is transferred in different ranks, as expressed by Sommerfeld's dictum "Thermodynamics investigates the conditions that govern the transformation of heat into work. It teaches us to recognize temperature as the measure of the work-value of heat. Heat of higher temperature is richer, is capable of doing more work. Work may be regarded as heat of an infinitely high temperature, as unconditionally available heat." This is why temperature is the particular variable indicated by the zeroth law's statement of equivalence.

In Carathéodory's (1909) theory, it is postulated that there exist walls "permeable only to heat", though heat is not explicitly defined in that paper. This postulate is a physical postulate of existence. It does not say that there is only one kind of heat. This paper of Carathéodory states as proviso 4 of its account of such walls: "Whenever each of the systems S1 and S2 is made to reach equilibrium with a third system S3 under identical conditions, systems S1 and S2 are in mutual equilibrium".: §6

It is the function of this statement in the paper, not there labeled as the zeroth law, to provide not only for the existence of transfer of energy other than by work or transfer of matter, but further to provide that such transfer is unique in the sense that there is only one kind of such wall, and one kind of such transfer. This is signaled in the postulate of this paper of Carathéodory that precisely one non-deformation variable is needed to complete the specification of a thermodynamic state, beyond the necessary deformation variables, which are not restricted in number. It is therefore not exactly clear what Carathéodory means when in the introduction of this paper he writes

It is possible to develop the whole theory without assuming the existence of heat, that is of a quantity that is of a different nature from the normal mechanical quantities.

It is the opinion of Lieb and Yngvason (1999) that the derivation from statistical mechanics of the law of entropy increase is a goal that has so far eluded the deepest thinkers.: 5 Thus the idea remains open to consideration that the existence of heat and temperature are needed as coherent primitive concepts for thermodynamics, as expressed, for example, by Maxwell and Planck. On the other hand, Planck (1926) clarified how the second law can be stated without reference to heat or temperature, by referring to the irreversible and universal nature of friction in natural thermodynamic processes.

Writing long before the term "zeroth law" was coined, in 1871 Maxwell discussed at some length ideas which he summarized by the words "All heat is of the same kind". Modern theorists sometimes express this idea by postulating the existence of a unique one-dimensional hotness manifold, into which every proper temperature scale has a monotonic mapping. This may be expressed by the statement that there is only one kind of temperature, regardless of the variety of scales in which it is expressed. Another modern expression of this idea is that "All diathermal walls are equivalent".: 23 This might also be expressed by saying that there is precisely one kind of non-mechanical, non-matter-transferring contact equilibrium between thermodynamic systems.

According to Sommerfeld, Fowler coined the term zeroth law of thermodynamics while discussing the 1935 text by Meghnad Saha and B.N. Srivastava.

They write on page 1 that "every physical quantity must be measurable in numerical terms". They presume that temperature is a physical quantity and then deduce the statement "If a bodyA is in temperature equilibrium with two bodiesB andC, thenB andC themselves are in temperature equilibrium with each other". Then they italicize a self-standing paragraph, as if to state their basic postulate:

Any of the physical properties ofA which change with the application of heat may be observed and utilised for the measurement of temperature.

They do not themselves here use the phrase "zeroth law of thermodynamics". There are very many statements of these same physical ideas in the physics literature long before this text, in very similar language. What was new here was just the label zeroth law of thermodynamics.

Fowler & Guggenheim (1936/1965) wrote of the zeroth law as follows:

... we introduce the postulate: If two assemblies are each in thermal equilibrium with a third assembly, they are in thermal equilibrium with each other.

They then proposed that

... it may be shown to follow that the condition for thermal equilibrium between several assemblies is the equality of a certain single-valued function of the thermodynamic states of the assemblies, which may be called the temperaturet, any one of the assemblies being used as a "thermometer" reading the temperaturet on a suitable scale. This postulate of the "Existence of temperature" could with advantage be known as the zeroth law of thermodynamics.

The first sentence of this present article is a version of this statement. It is not explicitly evident in the existence statement of Fowler and Guggenheim that temperature refers to a unique attribute of a state of a system, such as is expressed in the idea of the hotness manifold. Also their statement refers explicitly to statistical mechanical assemblies, not explicitly to macroscopic thermodynamically defined systems.

  1. Bailyn, M. (1994). A Survey of Thermodynamics, American Institute of Physics Press, New York, ISBN 0-88318-797-3, p. 22.
  2. Guggenheim, E.A. (1967). Thermodynamics. An Advanced Treatment for Chemists and Physicists, North-Holland Publishing Company., Amsterdam, (1st edition 1949) fifth edition 1965, p. 8: "If two systems are both in thermal equilibrium with a third system then they are in thermal equilibrium with each other."
  3. Buchdahl, H.A. (1966). The Concepts of Classical Thermodynamics, Cambridge University Press, Cambridge, p. 29: "... if each of two systems is in equilibrium with a third system then they are in equilibrium with each other."
  4. Carathéodory, C. (1909). "Untersuchungen über die Grundlagen der Thermodynamik" [Study of the fundamentals of thermodynamics]. Mathematische Annalen (in German). 67 (3): 355–386. doi:10.1007/BF01450409. S2CID 118230148.
    A translation may be found at "Carathéodory - Thermodynamics"(PDF). neo-classical-physics.info. A partly-reliable translation is given in
    Kestin, J. (1976). The Second Law of Thermodynamics. Stroudsburg PA: Dowden, Hutchinson & Ross.
  5. Maxwell, J. Clerk (1871). Theory of Heat. London, UK: Longmans, Green, and Co. p. 57.
  6. Bailyn, M. (1994). A Survey of Thermodynamics. New York, NY: American Institute of Physics Press. ISBN 978-0-88318-797-5.
  7. Lieb, E.H.; Yngvason, J. (1999). "The physics and mathematics of the second law of thermodynamics". Physics Reports. 310: 1–96.
  8. Planck, M. (1914). The Theory of Heat Radiation. Translated by Masius, M. (from 2nd German edition). Philadelphia, PA: P. Blakiston's Son & Co. p. 2.
  9. Buchdahl, H. A. (1966). The Concepts of Classical Thermodynamics. Cambridge University Press. p. 73.
  10. Kondepudi, D. (2008). Introduction to Modern Thermodynamics. Wiley. p. 7. ISBN 978-0470-01598-8.
  11. Dugdale, J. S. (1996). Entropy and its Physical Interpretation. Taylor & Francis. p. 35. ISBN 0-7484-0569-0.
  12. Sommerfeld, A. (1923). Atomic Structure and Spectral Lines, p. 36. London, UK: Methuen. (Translated from the third German edition by H.L. Brose.)
  13. Planck, M. (1926). "Über die Begründing des zweiten Hauptsatzes der Thermodynamik". S.B. Preuß. Akad. Wiss. phys. math. Kl.: 453–463.[full citation needed]
  14. Serrin, J. (1986). "Chapter 1, An outline of thermodynamical structure". In Serrin, J. (ed.). New Perspectives in Thermodynamics. Berlin, DE: Springer. pp. 3–32, esp. 6. ISBN 3-540-15931-2.
  15. Sommerfeld, A. (1951/1955). Thermodynamics and Statistical Mechanics, p. 1, vol. 5 of Lectures on Theoretical Physics, edited by F. Bopp, J. Meixner, translated by J. Kestin, Academic Press, New York.
  16. Saha, M.N., Srivastava, B.N. (1935). A Treatise on Heat. , p. 1. Allahabad and Calcutta: The Indian Press. (Including Kinetic Theory of Gases, Thermodynamics and Recent Advances in Statistical Thermodynamics) (The second and revised edition of A Text Book of Heat.)
  17. Fowler, R.; Guggenheim, E.A. (1965) [1939]. Statistical Thermodynamics (corrected ed.). Cambridge UK: Cambridge University Press. p. 56. A version of Statistical Mechanics for Students of Physics and Chemistry. (first printing 1939, reprinted with corrections 1965)

Zeroth law of thermodynamics
Zeroth law of thermodynamics Language Watch Edit The zeroth law of thermodynamics states that if two thermodynamic systems are each in thermal equilibrium with a third system then they are in thermal equilibrium with each other 1 2 3 Accordingly thermal equilibrium between systems is a transitive relation Two systems are said to be in thermal equilibrium with respect to each other if they are linked by a wall permeable only to heat and they do not change over time 4 As a convenience of language the same is also sometimes said of unlinked systems that would not change if they did have such a wall Another formulation by Maxwell is All heat is of the same kind 5 Another statement of the law is All diathermal walls are equivalent 6 24 144 The law is important for the mathematical formulation of thermodynamics Mathematically the zeroth law makes the relation of thermal equilibrium between systems an equivalence relation which is precisely the type of relation that can represent equality of some quantity associated to each system A quantity that is the same for two systems if and only if they can be placed in thermal equilibrium with each other is a scale of temperature the zeroth law is needed in order for there to exist any and therefore many such scales The condition justifies the use of practical thermometers 7 56 Contents 1 Equivalence relation 2 Foundation of temperature 3 Dependence on the existence of walls permeable only to heat 4 History 5 Citations 6 Further readingEquivalence relation EditA thermodynamic system is by definition in its own state of internal thermodynamic equilibrium that is to say there is no change in its observable state i e macrostate over time and no flows occur in it One precise statement of the zeroth law is that the relation of thermal equilibrium is an equivalence relation on pairs of thermodynamic systems 7 52 In other words the set of all systems each in its own state of internal thermodynamic equilibrium may be divided into subsets in which every system belongs to one and only one subset and is in thermal equilibrium with every other member of that subset and is not in thermal equilibrium with a member of any other subset This means that a unique tag can be assigned to every system and if the tags of two systems are the same they are in thermal equilibrium with each other and if different they are not This property is used to justify the use of empirical temperature as a tagging system Empirical temperature provides further relations of thermally equilibrated systems such as order and continuity with regard to hotness or coldness but these are not implied by the standard statement of the zeroth law If it is defined that a thermodynamic system is in thermal equilibrium with itself i e thermal equilibrium is reflexive then the zeroth law may be stated as follows If a bodyC be in thermal equilibrium with two other bodies AandB thenAandBare in thermal equilibrium with one another 8 This statement asserts that thermal equilibrium is a left Euclidean relation between thermodynamic systems If we also define that every thermodynamic system is in thermal equilibrium with itself then thermal equilibrium is also a reflexive relation Binary relations that are both reflexive and Euclidean are equivalence relations Thus again implicitly assuming reflexivity the zeroth law is therefore often expressed as a right Euclidean statement If two systems are in thermal equilibrium with a third system then they are in thermal equilibrium with each other 9 One consequence of an equivalence relationship is that the equilibrium relationship is symmetric If A is in thermal equilibrium with B then B is in thermal equilibrium with A Thus we may say that two systems are in thermal equilibrium with each other or that they are in mutual equilibrium Another consequence of equivalence is that thermal equilibrium is a transitive relationship and is occasionally expressed as such 7 56 10 IfAis in thermal equilibrium withBand ifBis in thermal equilibrium withC thenAis in thermal equilibrium withC A reflexive transitive relationship does not guarantee an equivalence relationship In order for the above statement to be true both reflexivity and symmetry must be implicitly assumed It is the Euclidean relationships which apply directly to thermometry An ideal thermometer is a thermometer which does not measurably change the state of the system it is measuring Assuming that the unchanging reading of an ideal thermometer is a valid tagging system for the equivalence classes of a set of equilibrated thermodynamic systems then the systems are in thermal equilibrium if a thermometer gives the same reading for each system If the system are thermally connected no subsequent change in the state of either one can occur If the readings are different then thermally connecting the two systems causes a change in the states of both systems The zeroth law provides no information regarding this final reading Foundation of temperature EditNowadays there are two nearly separate concepts of temperature the thermodynamic concept and that of the kinetic theory of gases and other materials The zeroth law belongs to the thermodynamic concept but this is no longer the primary international definition of temperature The current primary international definition of temperature is in terms of the kinetic energy of freely moving microscopic particles such as molecules related to temperature through Boltzmann s constant k B displaystyle k mathrm B The present article is about the thermodynamic concept not about the kinetic theory concept The zeroth law establishes thermal equilibrium as an equivalence relationship An equivalence relationship on a set such as the set of all systems each in its own state of internal thermodynamic equilibrium divides that set into a collection of distinct subsets disjoint subsets where any member of the set is a member of one and only one such subset In the case of the zeroth law these subsets consist of systems which are in mutual equilibrium This partitioning allows any member of the subset to be uniquely tagged with a label identifying the subset to which it belongs Although the labeling may be quite arbitrary 11 temperature is just such a labeling process which uses the real number system for tagging The zeroth law justifies the use of suitable thermodynamic systems as thermometers to provide such a labeling which yield any number of possible empirical temperature scales and justifies the use of the second law of thermodynamics to provide an absolute or thermodynamic temperature scale Such temperature scales bring additional continuity and ordering i e hot and cold properties to the concept of temperature 9 In the space of thermodynamic parameters zones of constant temperature form a surface that provides a natural order of nearby surfaces One may therefore construct a global temperature function that provides a continuous ordering of states The dimensionality of a surface of constant temperature is one less than the number of thermodynamic parameters thus for an ideal gas described with three thermodynamic parameters P V and N it is a two dimensional surface For example if two systems of ideal gases are in joint thermodynamic equilibrium across an immovable diathermal wall then P1V1 N1 P2V2 N2 where Pi is the pressure in the ith system Vi is the volume and Ni is the amount in moles or simply the number of atoms of gas The surface PV N constant defines surfaces of equal thermodynamic temperature and one may label defining T so that PV N RT where R is some constant These systems can now be used as a thermometer to calibrate other systems Such systems are known as ideal gas thermometers In a sense focused on in the zeroth law there is only one kind of diathermal wall or one kind of heat as expressed by Maxwell s dictum that All heat is of the same kind 5 But in another sense heat is transferred in different ranks as expressed by Sommerfeld s dictum Thermodynamics investigates the conditions that govern the transformation of heat into work It teaches us to recognize temperature as the measure of the work value of heat Heat of higher temperature is richer is capable of doing more work Work may be regarded as heat of an infinitely high temperature as unconditionally available heat 12 This is why temperature is the particular variable indicated by the zeroth law s statement of equivalence Dependence on the existence of walls permeable only to heat EditIn Caratheodory s 1909 4 theory it is postulated that there exist walls permeable only to heat though heat is not explicitly defined in that paper This postulate is a physical postulate of existence It does not say that there is only one kind of heat This paper of Caratheodory states as proviso 4 of its account of such walls Whenever each of the systems S1 and S2 is made to reach equilibrium with a third system S3 under identical conditions systems S1 and S2 are in mutual equilibrium 4 6 It is the function of this statement in the paper not there labeled as the zeroth law to provide not only for the existence of transfer of energy other than by work or transfer of matter but further to provide that such transfer is unique in the sense that there is only one kind of such wall and one kind of such transfer This is signaled in the postulate of this paper of Caratheodory that precisely one non deformation variable is needed to complete the specification of a thermodynamic state beyond the necessary deformation variables which are not restricted in number It is therefore not exactly clear what Caratheodory means when in the introduction of this paper he writes It is possible to develop the whole theory without assuming the existence of heat that is of a quantity that is of a different nature from the normal mechanical quantities 4 It is the opinion of Lieb and Yngvason 1999 7 that the derivation from statistical mechanics of the law of entropy increase is a goal that has so far eluded the deepest thinkers 7 5 Thus the idea remains open to consideration that the existence of heat and temperature are needed as coherent primitive concepts for thermodynamics as expressed for example by Maxwell and Planck On the other hand Planck 1926 13 clarified how the second law can be stated without reference to heat or temperature by referring to the irreversible and universal nature of friction in natural thermodynamic processes 13 History EditWriting long before the term zeroth law was coined in 1871 Maxwell 5 discussed at some length ideas which he summarized by the words All heat is of the same kind 5 Modern theorists sometimes express this idea by postulating the existence of a unique one dimensional hotness manifold into which every proper temperature scale has a monotonic mapping 14 This may be expressed by the statement that there is only one kind of temperature regardless of the variety of scales in which it is expressed Another modern expression of this idea is that All diathermal walls are equivalent 6 23 This might also be expressed by saying that there is precisely one kind of non mechanical non matter transferring contact equilibrium between thermodynamic systems According to Sommerfeld Fowler coined the term zeroth law of thermodynamics 15 while discussing the 1935 text by Meghnad Saha and B N Srivastava 16 They write on page 1 that every physical quantity must be measurable in numerical terms They presume that temperature is a physical quantity and then deduce the statement If a body A is in temperature equilibrium with two bodies B and C then B and C themselves are in temperature equilibrium with each other 16 Then they italicize a self standing paragraph as if to state their basic postulate Any of the physical properties of A which change with the application of heat may be observed and utilised for the measurement of temperature 16 They do not themselves here use the phrase zeroth law of thermodynamics There are very many statements of these same physical ideas in the physics literature long before this text in very similar language What was new here was just the label zeroth law of thermodynamics Fowler amp Guggenheim 1936 1965 17 wrote of the zeroth law as follows we introduce the postulate If two assemblies are each in thermal equilibrium with a third assembly they are in thermal equilibrium with each other 17 They then proposed that it may be shown to follow that the condition for thermal equilibrium between several assemblies is the equality of a certain single valued function of the thermodynamic states of the assemblies which may be called the temperature t any one of the assemblies being used as a thermometer reading the temperature t on a suitable scale This postulate of the Existence of temperature could with advantage be known as the zeroth law of thermodynamics 17 The first sentence of this present article is a version of this statement It is not explicitly evident in the existence statement of Fowler and Guggenheim that temperature refers to a unique attribute of a state of a system such as is expressed in the idea of the hotness manifold Also their statement refers explicitly to statistical mechanical assemblies not explicitly to macroscopic thermodynamically defined systems Citations Edit Bailyn M 1994 A Survey of Thermodynamics American Institute of Physics Press New York ISBN 0 88318 797 3 p 22 Guggenheim E A 1967 Thermodynamics An Advanced Treatment for Chemists and Physicists North Holland Publishing Company Amsterdam 1st edition 1949 fifth edition 1965 p 8 If two systems are both in thermal equilibrium with a third system then they are in thermal equilibrium with each other Buchdahl H A 1966 The Concepts of Classical Thermodynamics Cambridge University Press Cambridge p 29 if each of two systems is in equilibrium with a third system then they are in equilibrium with each other a b c d Caratheodory C 1909 Untersuchungen uber die Grundlagen der Thermodynamik Study of the fundamentals of thermodynamics Mathematische Annalen in German 67 3 355 386 doi 10 1007 BF01450409 S2CID 118230148 A translation may be found at Caratheodory Thermodynamics PDF neo classical physics info A partly reliable translation is given in Kestin J 1976 The Second Law of Thermodynamics Stroudsburg PA Dowden Hutchinson amp Ross a b c d Maxwell J Clerk 1871 Theory of Heat London UK Longmans Green and Co p 57 a b Bailyn M 1994 A Survey of Thermodynamics New York NY American Institute of Physics Press ISBN 978 0 88318 797 5 a b c d e Lieb E H Yngvason J 1999 The physics and mathematics of the second law of thermodynamics Physics Reports 310 1 96 Planck M 1914 The Theory of Heat Radiation Translated by Masius M from 2nd German edition Philadelphia PA P Blakiston s Son amp Co p 2 a b Buchdahl H A 1966 The Concepts of Classical Thermodynamics Cambridge University Press p 73 Kondepudi D 2008 Introduction to Modern Thermodynamics Wiley p 7 ISBN 978 0470 01598 8 Dugdale J S 1996 Entropy and its Physical Interpretation Taylor amp Francis p 35 ISBN 0 7484 0569 0 Sommerfeld A 1923 Atomic Structure and Spectral Lines p 36 London UK Methuen Translated from the third German edition by H L Brose a b Planck M 1926 Uber die Begrunding des zweiten Hauptsatzes der Thermodynamik S B Preuss Akad Wiss phys math Kl 453 463 full citation needed Serrin J 1986 Chapter 1 An outline of thermodynamical structure In Serrin J ed New Perspectives in Thermodynamics Berlin DE Springer pp 3 32 esp 6 ISBN 3 540 15931 2 Sommerfeld A 1951 1955 Thermodynamics and Statistical Mechanics p 1 vol 5 of Lectures on Theoretical Physics edited by F Bopp J Meixner translated by J Kestin Academic Press New York a b c Saha M N Srivastava B N 1935 A Treatise on Heat p 1 Allahabad and Calcutta The Indian Press Including Kinetic Theory of Gases Thermodynamics and Recent Advances in Statistical Thermodynamics The second and revised edition of A Text Book of Heat a b c Fowler R Guggenheim E A 1965 1939 Statistical Thermodynamics corrected ed Cambridge UK Cambridge University Press p 56 A version of Statistical Mechanics for Students of Physics and Chemistry first printing 1939 reprinted with corrections 1965 Further reading EditAtkins Peter 2007 Four Laws That Drive the Universe New York Oxford University Press ISBN 978 0 19 923236 9 Retrieved from https en wikipedia org w index php title Zeroth law of thermodynamics amp oldid 1046457700, wikipedia, wiki, book,

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